Updating Web Design Skillset

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Hi everybody its been a while since I have been on Certforums as I've been bashing away at my Network+ which I've now successfully passed. I've decided to have a break from any further Hardware studies as the next stage would be to study for my MCSA, which at the moment, without any real experience would be pretty pointless.

I've decided to concentrate back on updating my web design skills which I graduated in nearly four years ago. It has been a while since I even sat down and looked at anything in this, my question is what languages would people working within this field recommend to study? I am hoping to cover a few different bases. I'm fairly knowledgable on Dreamweaver and flash (although its been a while) I was intending to have a go at:

Apache and PHP
Flash and Actionscript
XHTML
DHTML
MySQL

That should keep me busy for a while, but if anybody has any suggestions for other languages or software that would be worth having a look at it would be most apprieciated.

 

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I'm falling for the Ajax toolkit at the moment, but it may even be worth while having a dig about Ajax aswell

 

Javascript, Jqeury and Ajax